At least in terms of his dapper personal grooming; you don't necessarily need to focus on the misogyny and regular brushes with death.
Learn to tie a bow-tie, so you can throw out your clip-on.
It looks as stunning with a flannel shirt as it does on a tuxedo.
Source: designyoutrust.com
Make your gloves touchscreen-sensitive.
All it takes is some conductive thread and you'll be a DIY spy in no time.
Source: instructables.com
Shave with a straight razor.
Don't worry, your level of manliness isn't actually dictated by whatever device you happen to shave with. But if you feel like having a major Bond grooming moment: straight razor shaving instructions are here.
Source: artofmanliness.com
Use a disposable razor to shave (and thereby save) a pilly piece of clothing.
Bond wouldn't be caught dead with fuzzballs on his sweater. Also, this is a great way to use all those plastic razors you won't need now that you have your straight one.
Source: pinterest.com